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While preparing a lecture on sound sequences in English words, I put up a list of 'illegal' initial consonant clusters, e.g. */pt_/. Words such as ptarmigan, pterodactyl or Ptolemy start with /t_/. I can't offer a word with initial /pt_/ or can you?
What about /ps_/? Yes, there a few:
psst
psi
and optionally though rare in
psittacosis
psoriasis
psephology